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KMID : 1024520050140020221
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Journal of the Environmental Sciences
2005 Volume.14 No. 2 p.221 ~ p.230
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On-stream Activity and Surface Chemical Structure of CoO₂/TiO₂ Catalysts for Continuous Wet TCE Oxidation
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Kim Moon-Hyeon
Choo Kwang-Ho
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Abstract
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Catalytic wet oxidation of trichloroethylene (TCE) in water has been conducted using cobalt oxides at with a weight hourly space velocity of , prepared by using an incipient wetness technique, might be the most promising catalyst for the wet oxidation although it exhibited a transient behavior in time on-stream activity. Not only could the bare support be inactive for the wet decomposition reaction, but no TCE removal also occurred by the process of adsorption on surface. The catalytic activity was independent of all particle sizes used, thereby representing no mass transfer limitation in intraparticle diffusion. XPS spectra of both fresh and used Co surfaces gave different surface spectral features for each binding energy for Co species in the fresh catalyst appeared at 781.3 eV, which is very similar to the chemical states of such as . The used catalyst exhibited a 780.3-eV main peak with a satellite structure at 795.8 eV. Based on XPS spectra of reference Co compound, the TCE-exposed Co surfaces could be assigned to be in the form of mainly . XRD patterns for catalyst indicated that the phase structure of Co species in the catalyst even before reaction is quite comparable to the diffraction lines of external standard. A model structure of present predominantly on titania surfaces would be , encapsulated in thin-film species consisting of and , which may be active for the decomposition of TCE in a flow of water.
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KEYWORD
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Heterogeneous Wet Catalysis, Cobalt Oxides, Trichloroethylene, Chlorinated Hydrocarbons, Surface Chemical States
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